Biaxial effects in modelling earthquake response of R/C structures

Recent studies reveal that R/C structural members subjected to biaxial flexure due to two-dimensional earthquake excitation can deform much more than would be predicted by conventional one-dimensional response analysis. The biaxial flexure may therefore have a significant effect on the dynamic collapse process of structures subjected to intense ground motions. The present paper is intended to develop a new formulation of the two-dimensional restoring force model of R/C columns acted upon by biaxial bending moments, and to discuss the dynamic response properties of R/C structures. The model considered is a two-dimensional extension of various non-linear models for one-dimensional response analysis, including the degrading trilinear stiffness model which is one of the simpler idealizations of the restoring force characteristics of flexural-failure-type R/C structures. The modelling validity is then examined by comparison with experimental data on the biaxial bending behaviour of R/C columns. Calculations are made to study the role of different system properties on the influence of inelastic biaxial bending on the dynamic structural response. It is shown that the inelastic biaxial effect is generally significant and, in some cases, critical in the case of R/C structures with stiffness-degrading properties, while the effect is not so important for the non-degrading inelastic cases.     

Young,olivine xenocryst-bearing alkali-basalt from the oceanward slope of the Japan Trench

Young (6 Ma) alkali-basalts were collected from the toe of the oceanward slope of the northern Japan Trench. Two types of olivine are present in these lavas, xenocrysts with reaction rims and magmatic. The forsterite (Fo) (no. 91–92) values and NiO contents (0.3–0.5 wt%) of the xenocrysts are similar in composition to those of the depleted mantle peridotite. The groundmass olivines have relatively lower Fo values (no. 81–88) and NiO contents (0.1–0.5 wt%). Reaction rims and the vicinity of the silicate inclusion in xenocrysts show the intermediate compositions between the xenocryst and magmatic olivines. Chromian spinel inclusions in the xenocrysts also show the depleted composition in the range of abyssal peridotite. CO₂ fluid inclusions in the xenocryst records pressures before entrainment into the host magma up to 0.4 GPa, which corresponds to a depth of up to 14 km of lithospheric mantle. These data indicate that the xenocrysts originate from MORB-depleted mantle.     

Dielectric anisotropy and deformation of crustal rocks: physical interaction theory and dielectric mylonites

The theory of physical interaction field by a differential geometrical approach combines the deformation field with the physical field (e.g., electromagnetic field), and derives a new tensorial relation between the deformation and the dielectric anisotropy of the crustal rocks. This relation can be applied to dielectric anisotropies of deformed natural rocks such as mylonites or gneisses. The dielectric anisotropies of mylonites are observed to increase as plastic strains of mylonites increase. Moreover, the derived tensorial relation can be linked to the electromagnetic potential field (deformational anomalies) in a deformed crust. A physico-geometrical consideration on this theory of physical interaction field is mathematically similar to ones on the theory of field in the Finsler space or on the concept of a unified gauge field.     

Exsolution textures in orthopyroxene in aluminous granulites as indicators of UHT metamorphism: New evidence from the Eastern Ghats Belt, India

Highly aluminous orthopyroxene, coexisting with sapphirine, cordierite, sillimanite, quartz and garnet in various combinations, constitute granoblastic mosaic peak metamorphic assemblages in aluminous granulites from three localities in the Eastern Ghats Belt, India. Orthopyroxene contains four types of intergrowths: (a) involving sapphirine with or without cordierite, (b) involving spinel, but without sapphirine, (c) involving cordierite, but without sapphirine and spinel, and (d) involving garnet, without sapphirine, spinel or cordierite. On the basis of textural and compositional data, origin of the intergrowths is ascribed to breakdown of Mg-Tschermak component, locally also involving Fe- and Ti-Tschermak. An attempt is made to compute the “pre-breakdown” compositions of orthopyroxene by image analysis, which shows maximum Al₂O₃ content of 13.4 wt.% in the pristine orthopyroxene. Geothermometry, phase equilibria consideration and application of existing experimental data on alumina solubility in orthopyroxene coexisting with sapphirine and quartz, collectively indicate extreme thermal conditions of metamorphism (> 1000 °C) for the studied assemblages. This re-affirms the notion that Al₂O₃ solubility in orthopyroxene is the most powerful indicator of UHT metamorphism (Harley, S.L., 2004. Extending our understanding of ultrahigh temperature crustal metamorphism. J. Mineral. Petrol. Sci. 99, 140–158). The intergrowths are considered to have formed due to cooling from the thermal peak spanning a temperature range of approximately 150 °C. Appearance of diverse types of intergrowths is probably related to subtle differences in bulk composition, particularly Fe:Mg ratios.     

Determination of Ti, K, Sm and Gd Values in Geological Survey of Japan Reference Materials by Prompt Gamma Neutron Activation Analysis

Prompt gamma neutron activation analysis was applied to the determination of the titanium, potassium, samarium and gadolinium contents of nine Geological Survey of Japan (GSJ) reference materials (JB-1, 1a, 2, 3; JA-1, 2, 3; JR-1, 2). Firstly, the values in JB-1 were determined by the standard addition method: pressed powder disks of JB-1 were used for neutron irradiation and gamma-ray measurements, after known quantities of standard reagents had been added. Secondly, the contents of eight other reference materials were determined by comparison methods using JB-1 as the comparative standard. The precision of analyses were obtained by replicate determinations on these samples. The relative standard deviation was generally less than 5%. For most samples, analysed values agreed well (< 5%) with the recommended values.     

Speciation of Chromium in Artificially Contaminated Soil Reference Material GSJ JSO-2 Using XANES and Chemical Extraction Methods

The oxidation states of chromium in GSJ JSO-2 (artificially contaminated soil) and three other geochemical reference materials (GSJ JSO-1, JLS-1 and JMS-1) were observed using X-ray near edge structure (XANES). For comparison, other artificially contaminated soil materials (mimic-JSO-2) were prepared by adding Cr(VI) into JSO-1. Their oxidation states of chromium were determined using XANES. The chromium contents were 1118 μg g^-1 for JSO-2, 1352 μg g^-1 for mimic-JSO-2 and 69-113 μg g^-1 for the other reference materials. Most chromium was present as hexavalent in mimic-JSO-2. No hexavalent species were detected in other samples. These results for chromium oxidation state in JSO-2 and mimic-JSO-2 obtained with XANES resembled those obtained from a chemical extraction method. The present JSO-2 has no trace of Cr(VI), although Cr(VI) was added as a major species during preparation. On the other hand, the content of Cr(VI) obtained in mimic-JSO-2 agreed with the original Cr(VI) content. A time-elapse study showed that Cr(VI) contents in mimic-JSO-2 decreased gradually to 70% of the original abundance during 240-day preservation in dry conditions. Moreover, the abundance of Cr(VI) decreased markedly to 15% after 240 days in the wet mimic-JSO-2 containing 20% m/m of water. These experiments suggested that soil humidity enhanced the reduction of Cr(VI) and that Cr(VI) was reduced even in dry conditions. Consequently, it is reasonable to infer that Cr(VI) doped into JSO-2 was completely reduced to Cr(III) during the preservation period of 5 years. The certification of the long-term stability of the chemical form in reference materials will be much more important in future.     

Middle Miocene to Quaternary primary basalt and high magnesian andesite magmas of North Hokkaido, Japan: Source mantle characteristics and degrees of partial melting

Abstract   Middle Miocene to Quaternary primitive basalts and high magnesian andesite (HMA) in North Hokkaido resulted from three periods of intense volcanism; early-stage (12–10 Ma), middle-stage (9–7 Ma) and late-stage (3–0 Ma). Based on the chemical compositions of olivines and chromian spinels and bulk chemistry of the primitive rocks, we examined depths of segregation of the calculated primary magmas and the degrees of partial melting of the source mantle. In the context of asthenospheric mantle upwelling, petrological data from the present study can be accounted for by the secular change in the depth of magma segregation from the upwelled asthenospheric mantle, which is composed of fertile peridotite. Thus, the early-stage primary magmas were generated by higher degrees of partial melting of the shallower part of hot asthenospheric mantle, whereas the middle- and late-stage primary magmas resulted from lower degrees of partial melting of a deeper part of the asthenospheric mantle. The early-stage HMA magma was generated by partial melting of the remnant subcontinental lithospheric mantle composed of refractory peridotite. This melting might have resulted from an increased geothermal gradient caused by upwelling of hot asthenosphere.     

Geochemical characteristics of Tertiary Sagara oil from an active forearc basin, Shizuoka, Japan

Abstract   The Sagara oil field is located in the Neogene Kakegawa Basin, close to the Izu collision zone at the junction between the main Japanese Islands and the Izu–Bonin Arc. The Sagara oil field is one of the few oil fields situated in a forearc basin on the Pacific side of Japan and is present in a sedimentary basin with poor oil-generating potential. Several crude oils from Sagara oil field were investigated to infer their origin. Organic geochemical characteristics of Sagara oils showed the influences of light biodegradation, migration-contamination, and migration-fractionation. The maturity levels of Sagara oils evaluated based on abundant alkylnaphthalenes corresponded to 0.9–1.2% vitrinite reflectance. Sagara oils were characterized by significant amounts of higher plant biomarkers, a high pristane/phytane ratio and an absence of organic sulphur compounds, suggesting a siliciclastic source rock deposited under nearshore to fluvial–deltaic environments. Numerous faults and fractures in the active forearc basin provided excellent conduits and facilitated upward migration of light hydrocarbons generated at greater depth in the Kakegawa Basin.     

Short-range prediction experiments of the Kuroshio path variabilities south of Japan

Assimilation and prediction experiments of the Kuroshio path variability south of Japan were conducted to investigate the predictability of the Kuroshio path. The assimilation and prediction system is composed of an eddy-resolving model and a three-dimensional variational analysis scheme with vertical coupled temperature–salinity empirical orthogonal function modes. The sea surface height (SSH) variability and the variations of the Kuroshio path of the assimilation fields are in good agreement with those observed. The results of the assimilation are then used as the initial conditions for 138 cases of 90-day prediction experiments conducted from 1993 to 2004. The predictive limit of our system is assessed by the SSH anomaly in the assimilation field and is found to be around 40–60 days, which is much longer than that of the persistence. The prediction results show good performance in the transition stage from a straight to a meandering path. For example, a large meandering event that occurred in August 2004 is successfully predicted in a 2-month forecast. Two types of failure cases are investigated. One is a case where the eastward propagation speed of the meander is faster than a real state. The dynamical response of the model to the assimilation revealed that an initial shock, caused by the dynamically unbalanced initial condition, induces the fast eastward propagation of the meander. The other case exhibits an unrealistic meander. In this case, a cold anomaly at an intermediate layer in the initial condition grows rapidly and results in the unrealistic meander. This implies that the Kuroshio path south of Japan has a chaotic nature. These facts revealed by the failure cases give us some insight for improving the predictive skill of the Kuroshio path variability.     

Secondary calcium-iron-rich minerals in the Bali-like and Allende-like oxidized CV3 chondrites and Allende dark inclusions

Abstract— We have characterized Ca-Fe-rich silicates (salite-hedenbergite pyroxenes (Fs_10–50Wo_45–50), andradite (Ca₃Fe₂Si₃O₁₂), kirschsteinite (CaFeSiO₄), and wollastonite (Ca₃Si₃O₉)) in the type I chondrules and matrices in the Bali-like and Allende-like oxidized CV3 chondrites and Allende dark inclusions. In type I chondrules in the Bali-like CV3 chondrites, metal is oxidized to magnetite; magnetite-sulfide nodules are replaced by Ca-Fe-rich pyroxenes with minor andradite and pure fayalite. We infer that Ca-Fe-rich pyroxenes, andradite, fayalite, magnetite, and phyllosilicates (which occur in mesostases) formed at relatively low temperatures (<300 °C) in the presence of aqueous solutions. Thermodynamic analysis of phase relations in the Si-Fe-Ca-O-H system and large O isotopic fractionation of the coexisting magnetite and fayalite (～20%) (Krot et al., 1998) are consistent with this interpretation. In type I chondrules in the Allende-like CV3 chondrites and dark inclusions, magnetite-sulfide nodules are replaced by Ca-Fe-rich pyroxenes and ferrous olivine; low-Ca pyroxene and forsterite phenocrysts are rimmed and veined by ferrous olivine. It appear that the Ca-Fe-rich pyroxenes predate formation of ferrous olivine; the latter postdates formation of talc and biopyriboles (Brearley, 1997). The Allende dark inclusions are crosscut by Ca-Fe-pyroxene-andradite veins and surrounded by Ca-rich rims that consist of Ca-Fe-rich pyroxenes, andradite, wollastonite, and kirschsteinite. Calcium-rich veins and rims formed after aggregation and lithification of the dark inclusions. The rimmed dark inclusions show zoned depletion in Ca, which is due to a lower abundance of Ca-Fe-rich pyroxenes close to the rim. Calcium was probably leached from the inclusions and redeposited along their edges. We infer that the Allende-like chondrites and dark inclusions experienced similar aqueous alteration to the Bali-like chondrites and were metamorphosed subsequently, which resulted in loss of aqueous solutions and dehydration of phyllosilicates. We conclude that Ca-Fe-rich silicates in the oxidized CV3 chondrites and Allende dark inclusions are secondary and resulted from aqueous fluid-rock interactions during progressive metamorphism of a heterogeneous mixture of hydrous (ices?) and anhydrous materials; the latter were possibly mineralogically similar to the reduced CV3 chondrites.